Titanocene Dichloride, bis(cyclopentadienyl titanium dichloride).

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TDC (Metal alkyls and complex metalorganics)

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TDC (Metal alkyls and complex metalorganics)

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  • United States+1
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  • Afghanistan (‫افغانستان‬‎)+93
  • Albania (Shqipëri)+355
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  • Angola+244
  • Anguilla+1
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  • Argentina+54
  • Armenia (Հայաստան)+374
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  • Ascension Island+247
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  • Azerbaijan (Azərbaycan)+994
  • Bahamas+1
  • Bahrain (‫البحرين‬‎)+973
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  • Barbados+1
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  • Lesotho+266
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  • Libya (‫ليبيا‬‎)+218
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  • Lithuania (Lietuva)+370
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  • Macau (澳門)+853
  • North Macedonia (Македонија)+389
  • Madagascar (Madagasikara)+261
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  • Malaysia+60
  • Maldives+960
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  • Malta+356
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  • Mauritania (‫موريتانيا‬‎)+222
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  • Mayotte+262
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  • Micronesia+691
  • Moldova (Republica Moldova)+373
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  • Mongolia (Монгол)+976
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  • New Caledonia (Nouvelle-Calédonie)+687
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  • Niger (Nijar)+227
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  • Niue+683
  • Norfolk Island+672
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  • Palau+680
  • Palestine (‫فلسطين‬‎)+970
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  • Russia (Россия)+7
  • Rwanda+250
  • Saint Barthélemy+590
  • Saint Helena+290
  • Saint Kitts and Nevis+1
  • Saint Lucia+1
  • Saint Martin (Saint-Martin (partie française))+590
  • Saint Pierre and Miquelon (Saint-Pierre-et-Miquelon)+508
  • Saint Vincent and the Grenadines+1
  • Samoa+685
  • San Marino+378
  • São Tomé and Príncipe (São Tomé e Príncipe)+239
  • Saudi Arabia (‫المملكة العربية السعودية‬‎)+966
  • Senegal (Sénégal)+221
  • Serbia (Србија)+381
  • Seychelles+248
  • Sierra Leone+232
  • Singapore+65
  • Sint Maarten+1
  • Slovakia (Slovensko)+421
  • Slovenia (Slovenija)+386
  • Solomon Islands+677
  • Somalia (Soomaaliya)+252
  • South Africa+27
  • South Korea (대한민국)+82
  • South Sudan (‫جنوب السودان‬‎)+211
  • Spain (España)+34
  • Sri Lanka (ශ්‍රී ලංකාව)+94
  • Sudan (‫السودان‬‎)+249
  • Suriname+597
  • Svalbard and Jan Mayen+47
  • Sweden (Sverige)+46
  • Switzerland (Schweiz)+41
  • Syria (‫سوريا‬‎)+963
  • Taiwan (台灣)+886
  • Tajikistan+992
  • Tanzania+255
  • Thailand (ไทย)+66
  • Timor-Leste+670
  • Togo+228
  • Tokelau+690
  • Tonga+676
  • Trinidad and Tobago+1
  • Tunisia (‫تونس‬‎)+216
  • Turkey (Türkiye)+90
  • Turkmenistan+993
  • Turks and Caicos Islands+1
  • Tuvalu+688
  • U.S. Virgin Islands+1
  • Uganda+256
  • Ukraine (Україна)+380
  • United Arab Emirates (‫الإمارات العربية المتحدة‬‎)+971
  • United Kingdom+44
  • United States+1
  • Uruguay+598
  • Uzbekistan (Oʻzbekiston)+998
  • Vanuatu+678
  • Vatican City (Città del Vaticano)+39
  • Venezuela+58
  • Vietnam (Việt Nam)+84
  • Wallis and Futuna (Wallis-et-Futuna)+681
  • Western Sahara (‫الصحراء الغربية‬‎)+212
  • Yemen (‫اليمن‬‎)+967
  • Zambia+260
  • Zimbabwe+263
  • Åland Islands+358

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TDC (Metal alkyls and complex metalorganics)

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  • ProductChemicalFamily

    Metal Alkyls organometallics
  • ProductCASnr

    1271-19-8
  • ProductPhysicalForm

    Powder
  • Regional availability

    Asia, Asia Pacific, China
  • ProductMolecularWeight

    249.0
  • ProductChemicalsName

    Titanocene Dichloride, bis(cyclopentadienyl titanium dichloride)
  • Molecular drawing

    Metal Alkyls organometallics
  • ProductApplications

    Hydrogenation of rubbers: Titanocene Dichloride and derivatives are used as hydrogenation catalyst for rubbers, like SBS and SEBS, to improve heat stability and resistance to ozone/oxidation [1]. Polymerization: Titanocene Dichloride can be used with polymethylaluminoxane as a catalyst for metallocene type olefin polymerizations [2]. Organic synthesis: Titanocene Dichloride is a useful reagent for a wide variety of synthetic transformations. It can be used with Grignard reagents for the reduction of aryl and vinyl halides [3]; with magnesium for the reduction of organic halides, azo compounds, haloketones, and haloesters [4]; with sodium for the reduction of aliphatic aldehydes, esters, and epoxides [5]; for the reductive decyanation of alkyl nitriles [6]; and the reduction of olefins [7]. Titanocene Dichloride has been used with alkylaluminum compounds for the alkylation of α-olefins [8] and alkynylsilanes [9]. It can be reacted with trimethylaluminum to form Tebbe reagent, which is used to transform a carbonyl into a methylene group [10]. Nouryon can further convert Titanocene Dichloride into derivatives required by the customer, e.g. by substituting the Cl-atoms by other groups or by replacing the cyclopentadienyl rings with substituted cyclopentadienyl rings.

Use Cases

Polymer production

MsbLongDescription

TDC is used as a hydrogenation catalyst for rubber, as a primary catalyst for olefin polymerization reactions, and for organic synthesis reactions.

ProductFunctions

  • Cocatalyst

MsbApplications

  • Rubber,
  • Polyethylene
Read more

Pharmaceutical industry

MsbLongDescription

TDC is used for organic synthesis reactions like carbonyl methylenation.

ProductFunctions

  • Chemical Reagent

MsbApplications

  • Pharmaceutical and Fine Chemicals
Read more

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